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Crude-specific optimal operation of hydrodesulfurization
Mälardalen University, School of Business, Society and Engineering, Future Energy Center.ORCID iD: 0000-0002-1240-5449
Mälardalen University, School of Innovation, Design and Engineering, Innovation and Product Realisation.ORCID iD: 0000-0002-2978-6217
Mälardalen University, School of Business, Society and Engineering, Future Energy Center.ORCID iD: 0000-0002-8466-356X
2021 (English)In: Chemical Engineering Transactions, ISSN 1974-9791, E-ISSN 2283-9216, Vol. 86, p. 961-966Article in journal (Refereed) Published
Abstract [en]

Crude oil has different characteristics according to its origin, and this difference causes suboptimal operation if not considered. Similar to other refinery operations, hydrodesulfurization suffers from lacking this knowledge. Information on the true boiling point curve of the feed, next to its sulfur concentration, can be used to optimize the operating temperature. In this work, an optimization problem is demonstrated for two manipulated temperatures of the system and solved by using a gradient-based and a gradient-free algorithm. While the gradient based solution has a single objective of minimum sulfur content, the gradient-free solution has three objectives: minimum sulfur, inlet temperature, and secondary hydrogen flow rate. A continuous lumping model is used to predict the temperature and sulfur responses of a real hydrodesulfurization plant. An adaptive approach is preferred for the model to cope with the catalyst deactivation interference on the product sulfur content constraint. The effect of changing feed on optimality is demonstrated by using eight types of feeds with varying true boiling point and sulfur content. In addition to that, the impact of catalyst age is shown on similar feed processed on different dates.

Place, publisher, year, edition, pages
Italian Association of Chemical Engineering - AIDIC , 2021. Vol. 86, p. 961-966
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:mdh:diva-55529DOI: 10.3303/CET2186161Scopus ID: 2-s2.0-85109525191OAI: oai:DiVA.org:mdh-55529DiVA, id: diva2:1583140
Available from: 2021-08-05 Created: 2021-08-05 Last updated: 2025-10-10Bibliographically approved
In thesis
1. Energy savings for petroleum processing: Using mathematical models, optimal control and diagnostics
Open this publication in new window or tab >>Energy savings for petroleum processing: Using mathematical models, optimal control and diagnostics
2023 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Petroleum products are widely used as an energy supply, and the total production capacity of petroleum refineries is quite high. In this thesis, an energy intensive refinery process, hydroprocessing, is selected and evaluated in terms of its energy loss contributors. Digital solutions are discussed and demonstrated to reduce losses. Both hydrotreatment and hydrocracking processes are included in the evaluation since both require elevated temperatures due to the relevant reactions. While the former is the removal of undesired atoms, the latter is the production of short chain hydrocarbons from heavy oil. Both these processes contribute to cleaner fuel production.

When these processes are carried out in fixed bed reactors, the catalyst ages over time, slowing the reactions. Understanding the changes in system dynamics enables the control system to calculate the necessary temperature adjustments to facilitate stable product quality. The usual response is increasing the temperature, which adds to the heat load. If reaction rates are known, the temperature increase can be kept to a minimum. Obtaining real-time feed quality information can aid flexible feed processing refineries intensely. With real-time feed characterization, it is possible to use a feed forward model predictive control system to optimize reactor temperatures. Therefore, for varying crude oil quality, the control system can estimate the minimum temperature requirements for the product to be in the desired quality interval. Additional notice should be given to the temperature sensors as they supply data to the suggested control architecture. Wrong measurements threaten the optimality of the estimated control response. Faulty sensors should be detected and replaced to minimize the risk and collect correct data.

Observations made in this thesis show the possible energy gain for hydroprocessing by understanding the aging catalyst, soft sensor installation, feed forward model predictive control, and sensor fault detection. Hydroprocessing is a relevant topic for biorefineries. Although the demonstrations in this work are only for petroleum refineries, the suggested methods can be used in biorefineries as well as integrated co-processing petroleum and biorefineries.

Place, publisher, year, edition, pages
Västerås: Mälardalens universitet, 2023
Series
Mälardalen University Press Dissertations, ISSN 1651-4238 ; 372
National Category
Chemical Engineering
Research subject
Energy- and Environmental Engineering
Identifiers
urn:nbn:se:mdh:diva-61618 (URN)978-91-7485-581-4 (ISBN)
Public defence
2023-03-21, Gamma, Mälardalens universitet, Västerås, 09:00 (English)
Opponent
Supervisors
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FUDIPO
Available from: 2023-01-25 Created: 2023-01-25 Last updated: 2025-10-10Bibliographically approved

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Iplik, EsinAslanidou, IoannaKyprianidis, Konstantinos

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